Réactivité de l’acide déhydroacétique hydrogené en c5-c6 : obtention des pyrano-1,5-benzodiazépines différemment substituées et de la structure enaminone

A number of 1,5-benzodiazepines derivatives 4 were obtained via the interaction of dehydroacetic acid hydrogenated at C₅-C₆, orthophenylenediamines and aromatic aldehydes. The interpretation of the results is enriched by a study of the electronic effects of the DHA hydrogenated at C₅-C₆. Accordingly, it leads us to obtain the original structure cynnamoyle 5.     

Distribution of nonliner relaxation (DNLR) approach of the annealing effects in semicristalline polymers: structure–property relation for high-density polyethylene (HDPE)

This work is devoted to the numerical and experimental study of annealing effects on microstructure and mechanical properties of the high-density polyethylene (HDPE). Uniaxiale tension tests are conducted at 25 °C in order to characterize the mechanical behavior of HDPE. The influence of the annealing treatment on the material microstructure is examined by the Fourier transform infrared spectroscopy, and microstructures are characterized using differential scanning calorimetry. The distribution of nonlinear relaxation approach is adopted to describe the mechanical response of virgin and annealed HDPE. Annealing effects are incorporated into the constitutive model by introducing the microstructure (crystallinity degree) evolution on the macroscopic response of the material. The numerical predictions of the model are in good agreement with experimental results for the different states of the material.     

Synthesis,characterization, and application of sol gel derived Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript> powder

This paper reports a successful preparation of a pure forsterite Mg₂SiO₄ using the sol–gel approach and its application for the removal of impurities from a Tunisian frying oil. Magnesium nitrate hexahydrate and tetraethylortho-silicate were used as magnesium and silicon precursors, respectively. The synthesis was held at different calcination temperatures for 30?min. The annealed samples were characterized by X-ray diffraction, Fourier transform infrared, scanning electron microscopy, and laser diffraction. The results revealed that the sample calcined at 500?°C was forsterite with unimodal particle size distribution (PSD) centered at 122.8?±?0.3?μm. The dispersion index I (indicator of particle size uniformity) was 1.84. With the temperature increase, well crystallized compounds were obtained. Their PSDs remain unimodal and shift towards smaller particles. A decrease of the dispersion index was also noted, indicating the formation of Mg₂SiO₄ with more uniform particle size. This study showed that 900?°C could be selected as energy saving temperature suitable for the preparation of a pure and well crystallized Mg₂SiO₄ within just 30?min of annealing time. The obtained silicate exhibited promoting results for the purification of waste frying oils.

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Pure and fine Mg₂SiO₄ powder with unimodal particle size distribution was prepared by sol gel route under energy saving conditions. The obtained magnesium orthosilicate showed excellent results for waste frying oil purification

     

On the existence of the stabilizing solution of generalized Riccati equations arising in zero-sum stochastic difference games: the time-varying case

In this paper, a large class of time-varying Riccati equations arising in stochastic dynamic games is considered. The problem of the existence and uniqueness of some globally defined solution, namely the bounded and stabilizing solution, is investigated. As an application of the obtained existence results, we address in a second step the problem of infinite-horizon zero-sum two players linear quadratic (LQ) dynamic game for a stochastic discrete-time dynamical system subject to both random switching of its coefficients and multiplicative noise. We show that in the solution of such an optimal control problem, a crucial role is played by the unique bounded and stabilizing solution of the considered class of generalized Riccati equations.     

Chemical composition,antioxidant and antibacterial properties of Pteranthus dichotomus from Algerian Sahara

The phytochemical study of ethyl acetate and n-butanol extracts of Pteranthus dichotomus Forssk. led to the isolation and identification of 11 compounds, including three glycolipids 1–3, one lignan 4, three flavonoids 5–7 and four phytosterols 8–11. Structures of the isolated compounds have been elucidated by analysis of 1D and 2D NMR data, and mass spectrometry EI-MS and ESI-MS and by comparison with literature data. Furthermore, the ethyl acetate and n-butanol extracts were examined for their antioxidant and antibacterial activities. The results showed that both extracts (PDAC and PDBU) had a moderate antioxidant activity (IC50 = 375.514 μg/mL and 691.333 μg/mL) respectively.